The sum of probabilities of all outcomes in an experiment is
Probability of an event, P(E) = number of favourable outcomestotal number of outcomes
Let us take an example of tossing a coin. The possible outcomes of this experiment are {H, T}. That is, the total number of outcomes is 2.
Probability of getting a head, P(H) = 12
Probability of getting a tail, P(T) = 12
P(H) + P(T) = 12 + 12=1
⇒ The sum of probabilities of all outcomes in an experiment is 1.