The synthesis of 3−octyne is achieved by adding a bromoalkane into a mixture of sodium amide and an alkyne. The bromoalkane and alkyne respectively are:
A
BrCH2CH2CH2CH3 and CH3CH2C≡CH
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B
BrCH2CH2CH3 and CH3CH2CH2C≡CH
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C
BrCH2CH2CH2CH2CH3 and CH3C≡CH
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D
BrCH2CH2CH2CH3 and CH3CH2C≡CH
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Solution
The correct option is DBrCH2CH2CH2CH3 and CH3CH2C≡CH CH3−CH2−C≡CHNaNH2→CH3−CH2−C≡C−Na++CH3−CH2−CH2−CH2 Br+CH3−CH2−C≡C−Na+→CH3−CH2−CH2−CH2−C≡C−CH2−CH3