The table shown below gives the bond dissociation energies (Ediss) for single covalent bonds of carbon (C) atoms with the element P,Q,R and S. Which element has the smallest atoms?
Bond
Ediss(kJmol−1)
C−P
240
C−Q
328
C−R
276
C−S
485
A
P
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B
S
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C
R
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D
Q
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Solution
The correct option is BS The element ′S′ has the smallest atoms. It corresponds to strongest C−S bond and maximum bond dissociation energy (485 kJ/mol). Smaller is the bond length, stronger is the bond and higher is the bond dissociation energy.