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Question

The thermal stability of alkaline earth metal carbonates–MgCO3, CaCO3, SrCO3 and BaCO3, follows the order:

A
BaCO3>SrCO3>CaCO3>MgCO3
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B
CaCO3>SrCO3>BaCO3>MgCO3
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C
MgCO3>CaCO3>SrCO3>BaCO3
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D
SrCO3>CaCO3>MgCO3>BaCO3
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Solution

The correct option is A BaCO3>SrCO3>CaCO3>MgCO3
MCO3ΔMO+CO2

On moving down the group, the thermal stability increases due to the increase in electropositive character of the alkaline earth metals. The smaller the positive ion, the higher the charge density, and greater the effect it will have on the carbonate ion. As the positive ions get larger down the group, their effect on the carbonate ions near them decreases and therefore more heat must be supplied for the carbon dioxide to leave the metal oxide.

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