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Standard XII
Chemistry
Positional Isomerism
The total num...
Question
The total number of possible isomers for squar-planar
[
P
t
(
C
l
)
(
N
O
2
(
N
O
3
S
C
N
)
]
2
−
is:
A
8
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B
12
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C
16
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D
24
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Solution
The correct option is
B
12
This complex is of the form Mabcd which has the following isomers
But carefully observing the complex
Im
S
⋅
C
≡
¨
N
both S and n can donate lp
Im
N
O
2
both N and O can donate lp
Thus, the total number of isomers will be
(
2
×
2
)
×
3
=
12
due to
S
⋅
C
≡
N
:
duce to
N
O
2
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