Given, lateral surface area of a cube =216 cm2.
We know, total surface area of cube =6(a)2 where a is the length of its side.
∴6(a)2=216
⟹(a)2=2166
⟹(a)2=36
⟹ a =6.
Also, volume of cube =( a)3.
∴ Volume of cube =(6)3=216 cm3.