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Question

The true statement(s) regarding the complex [Cu(NH3)4]2+ is/are:
  1. It is paramagnetic, having one unpaired electron
  2. It is a square planar complex
  3. The hybridisation of the central atom is sp3
  4. EAN for copper is 36


Solution

The correct options are
A It is paramagnetic, having one unpaired electron
B It is a square planar complex
In [Cu(NH3)4]2+, Cu exists in +2 oxidaion state.

EAN= 29-2+8=35

The hybridisation of the complex is dsp2 and it is square planar.

It is paramagnetic and has one unpaired electron.

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