The two compounds pentaamminesulphatocobalt (III) bromide and pentaamminesulphatocobalt (III) chloride respresent :
A
Linkage isomerism
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B
Ionization isomerism
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C
Coordination isomerism
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D
No isomerism
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Solution
The correct option is D No isomerism Pentaamminesulphatocobalt (III) bromide is [Co(SO4)(NH3)4]Br and Pentaamminesulphatocobalt (III) chloride is [Co(SO4)(NH3)5]Cl.
The two compounds have different counter ion attached to it so its molecular mass will be different. Hence, they doesnot show any isomerism relationship.