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Coordination Isomerism

The type of i...

Question

The type of isomerism shown by $[C o (e n)_{2} (N C S)_{2}] C l$ and $[C o (e n)_{2} (N C S)] C l$ is :

A

ionization

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B

cordination

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C

linkage

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D

all of these

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Solution

The correct option is B linkage
Linkage isomers are coordination compounds that have the same composition but differ in the connectivity of the ligand to the metal. For example, a thiocyanato group could be connected to the metal atom by either the S atom or the N atom thiocyanate, $S C N^{⁻}$ and isothiocyanate, $N C S^{⁻}$

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[C o (e n)_{2} (N C S)_{2}] B r

[C o (e n)_{2} (B r)_{2}] N C S

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[C r (N H_{3})_{5} C l] B r

and the type of isomerism exhibited by these two complexes are :

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