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Question

The unit cell of a metallic element of atomic mass 108 and density 10.5 g/cm3 is a cube with edge length of 409 pm. The structure of the crystal lattice is:

A
fcc
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B
bcc
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C
hcp
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D
None of these
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Solution

The correct option is A fcc

We know that,

Density-

d=Z×Ma3×NA


Given :

Molar Mass(M)=108g/mol

Density (d)=10.5g/cm3

Edge Length(a)=409pm


Z=d×a3×NAM

Value of NA is NA=6.023×1023


Z=10.5×(409×1010cm3)3×6.023×1023108=4


Number of atoms =4


Hence the element is packed in FCC structure.


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