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Question

The unit of ionic product of water (Kw) is:

A
mol L1
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B
mol2 L2
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C
L mol1
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D
mol2 L2
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Solution

The correct option is B mol2 L2
Ionic Product of water:
H2O(l) + H2O (l)H3O+ (aq.)+ OH (aq.) or H2O(l)H3O+(aq) + OH(aq).
As per laws of mass action : Kc=[H+][OH][H2O]Kc×[H2O]=Kw=[H+][OH]
We can see that units of Kw are equal to units of [H+]×[OH]
Units of [H+]=[OH]=mol L1Kw=(mol L1)2=mol2L2

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