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Question

The value of ΔG(kJmol1) for the given cell is (take 1F=96500Cmol1):

A
-5.7
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B
5.7
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C
11.4
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D
-11.4
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Solution

The correct option is D -11.4
M|M2+ (saturated solution of a sparingly soluble salt MX2)||M2+0.001moldm3|M
Reactions of cell
At anode : M(s)M2+(aq.)+2e
At cathode : M2+(aq.)+2eM(s)
So no of reactions taking part in reaction is 2
Also, as we know
ΔG=nFE
ΔG=nFEcell=2×96500×0.059=113873kJ/mol
=11.387kJ/mol=11.4kJ/mole


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