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B
17.92
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C
−180
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D
10
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Solution
The correct option is B17.92 ΔH⊖=ΔH⊖P−ΔH⊖R;(for1mol) =[−1575.0kJmol−1−32×241.8]−[−2021.0kJmol−1] =+83.3kJmol−1 For 1 Kg CaSO4⋅2H2O Numebr of moles =1000172 =5.81 ∴ Heat change for 5.81molofCaSO4⋅2H2O=5.81×83.3kJmol−1 =484kJmol−1 ΔG=ΔH−TΔS =17.92kJ ........ (ΔS=SP−SR)