The value of ΔH−ΔU for the following reaction at 27∘ will be : 2NH3(g)→N2(g)+3H2(g)
8.314 ×273 ×( -2) J
8.314 ×300×( -2) J
- 800R
8.314×300×2 J
2NH3⇋N2+3H2 (g) (g) (g)ΔH=ΔU+ΔnRTΔn=4−2=(2)ΔH=ΔU=ΔnRT=−2×8.314×300JR=2cal,R=8.3145
Rate of disappearance of the reactant A in the reversable and one step reaction A⇌B at two temperatures is given by −d[A]dt=2.0×10−3s−1[A]−5.0×10−4s−1[B](at 27∘C)−d[A]dt=8.0×10−2s−1[A]−4.0×10−3s−1[B](at 127∘C) The enthapy of the reaction in the given temperature range is