Vant Hoff's Equation and Effect of Temperature on Equilibrium Constant
The value of ...
Question
The value of log10K for a reaction A⇌B is: (Given ΔrH0298K=−54.07kJmol−1,ΔrSo298K=10JK−1mol−1, R=8.314JK−1mol−1; and 2.303×8.314×298=5705Jmol−1)
A
5
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B
10
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C
95
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D
100
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Solution
The correct option is B 10 We know, ΔGo=ΔHo−TΔSo ⇒ΔGo=(−54.07×103−298×10)Jmol−1 ⇒ΔGo=−57050Jmol−1 Again, ΔGo=−RTlnK ⇒logK=ΔGo2.303RT ⇒logK=570505705=10