The value of log10K for a reaction A⇌B is:
Given: △rH298K=−54.07kJmol−1,△rSo298K=10JK−1mol−1andR=8.314JK−1mol−1;2.303×8.314×298=5705).
A
5
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B
10
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C
95
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D
100
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Solution
The correct option is B 10 Given- △rH298K=−54.07kJmol−1 △rSo298K=10JK−1mol−1 R=8.314JK−1mol−1 2.303×8.314×298=5705)
we know- △Go=△Ho−T△So =−54.07×103−(298)(10)Jmol−1 =−57050Jmol−1
We know, △Go=−2.303RTlogKo log10Ko=△Go2.303RT=57050Jmol−15705Jmol−1=10
hence, log10Ko=10