The value of molar conductivity of HCl is greater than that of NaCl at a particular temperature because
(1) molecular mass of HCl is less than that of NaCl
(2) velocity of H+ ion is more than that of Na+ ions
(3) HCl is strongly acidic
(4) ionisation of HCl is larger than that of NaCl

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Solution

Option b
H+ ion is smaller than Na+ ion , due to which it moves faster in the solution of the electrolytes .
Thats why the molar conductivity of HCl is higher than that of NaCl .

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