The value of Peltier coefficient of a thermocouple
The Peltier Coefficient represents the heat current flowing per unit charge through the material and does not vary with absolute temperature.
Consider two materials joined together with current flowing in a particular direction as shown. Now, the upper junction gets heated acquiring a temperature T2 and lower junctions remains at a lower temperature T1.
The Peltier heat absorbed by the lower junction per unit time Q is given by
Q′=πABI=[πA−πB]AI
piAB --- Peltier Coefficient of the entire circuit
piA --- Peltier Coefficient of material A
piB --- Peltier Coefficient of material B
The heat current shows discontinuity at the junctions because piA and piB are different.