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Question

The value of the ratio CpCv for H2 is 1.67 at 30k but decreases to 1.4 at 300K as more degrees of freedom become active. During this rise in temperature,

A
Cp remains constant but Cv increases
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B
Cp decreases but Cv increases
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C
Both Cp and Cv decreases by the same amount
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D
Both Cp and Cv increases by the same amount
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Solution

The correct option is D Both Cp and Cv increases by the same amount
When Δof increases, more heat required to raise the temperature as the heat has to be distributed to new Δofs.

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