The van der Waal's parameters for gases A, B, C and D are:
Gas
a(litre2atm/mol2)
b ( litre/mol)
A
4.0
0.027
B
8.0
0.030
C
6.0
0.032
D
12.0
0.027
Which one of these gases has the highest critical temperature?
A
A
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B
B
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C
C
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D
D
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Solution
The correct option is DD As we know, Critical temperature Tc=8a27Rb and among given values a/b value is highest for D so critical temperature is highest for D.