The Vander Waal's parameters for gases W, X, Y and Z are
Gasa (atm L2 mol−2)b (L mol−1)W4.00.027X6.00.030Y8.00.032Z12.00.027
Which one of these gases has the highest critical temperature?
Tc=8a27Rb
a/b ratio is maximum for Z.
Points to remember:
Pc=a27b2, Vc=3nb