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Question

The vander waals constants for gases A,B and C are as follows.
Gas a/dm6kPamol2 b/dm3mol1
A 405.3 0.027
B 1215.0 0.030
C 607.05 0.032

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Solution

(A) The gas A has lowest values of the vander waals constants a and b. Hence, it shows most ideal behavior around STP
(B) The gas B has highest value of the vander waals constant a . Hence, it has the highest critical temperature
(C) The gas B has highest value of the vander waals constant b. Hence, it has the largest molecular volume.

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