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Question

The vapour pressure of a pure liquid A is 40 mm of Hg at 310 K. The vapour pressure of this liquid in a solution with liquid B is 32 mm of Hg. The mole fraction of A in the solution, if it obey's Raoult's law, is?

A
0.8
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B
0.5
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C
0.2
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D
0.4
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Solution

The correct option is A 0.8
PA = 40mm of Hg
PT =32 mm of Hg
By Roult's Law, PT=PA×XA
32= XA× 40
XA=3240
XA=0.8
Therefore, mole fraction of A in the solution is 0.8

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