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Question

The vapour pressure of a pure liquid A is 70 torr at 27oC. It forms an ideal solution with another liquid B. The mole fraction of B is 0.2 and total vapour pressure of the solution is 84 torr at 27oC. The vapour pressure of pure liquid B at 27oC.

A
14
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B
56
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C
140
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D
70
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Solution

The correct option is D 140
Here we will use the simple total vapour pressure equation:

PT=xAPoA+xBPoB

84 torr=0.8×70 torr+0.2×PoB

PoB=140 torr .

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