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Question

The vapour pressure of pure benzene and toluene are 160 and 60 torr respectively. The mole fraction of toluene in the vapour phase in contact with an equimolar solution of benzene and toluene is :

A
0.5
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B
0.6
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C
0.27
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D
0.73
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Solution

The correct option is B 0.27
For the equimolar solution of benzene and toluene, the mole fraction of benzene and toluene are 0.5 each.

Total pressure P=PB+PT=P0BXB+PoTXT

P=160×0.5+60×0.5

P=110

The mole fraction of toluene in the vapour phase in contact with an equimolar solution of benzene and toluene.

YT=PTP

YT=PoTXTP

YT=60×0.5110=0.27

Hence, the correct option is C.

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