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Question

The vapour pressure of water at 80 C is 355 mm of Hg. A 100 ml vessel contains water saturated with O2 at 80 C the total pressure being 760 mm of Hg. The contents of the vessel were pumped into a 50 ml vessel at the same temperature, what is the partial pressure of O2?

A
1115 mm
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B
810 mm
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C
405 mm
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D
355 mm
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Solution

The correct option is B 810 mm
Volume of O2 = 100 ml
pO2=760355=405 mm
Since the temperature is constant,
Using Boyle's law we get,
100×405=50×pO2
pO2=810 mm

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