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Question

The volume of chlorine gas at STP (in Litres) required to completely react with 5 moles of hot and concentrated NaOH solution is:

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Solution

When chlorine gas reacts with hot and concentrated NaOH solution, it disproportionates into Cl and ClO3 ions.

3Cl2+6NaOH5NaCl+NaClO3+3H2O

The moles of Cl2 gas required to react with 5 moles of NaOH = 2.5 mol
So, the volume of Cl2 gas required at STP is 56 L

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