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Question

The volume of gases in litre evolved by passing 0.965A current for 1 hr through an aqueous solution of CH3COONa at 25oC and 1 atm is__________. (write the nearest integer value)

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Solution

The number of faradays of electricity passed =I(A)×t(s)96500=0.965×360096500=0.036
2CH3COONa+2H2OC2H6+2CO2+2NaOH+H2
The number of moles of gases liberated 2×0.036=0.072
The volume of gases liberated nRTP=0.072×0.0821×2981=1.762L.

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