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Question

The volume of phosgene formed at STP when 11.2 litres of Carbon monoxide reacts with chlorine gas is:

A
11.2 litres
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B
22.4 litres
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C
5.6 litres
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D
44.8 litres
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Solution

The correct option is C 11.2 litres
The reaction is CO+Cl2COCl2.
One mole of CO gives one mole of phosgene.
At STP, one mole of any gas occupies 22.4 L.
22.4 L of CO will give 22.4 L of phosgene at STP.
Thus, 11.2 L of CO will give 11.2 L of phosgene.

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