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Question

The volume of the reaction vessel containing an equilibrium mixture in the reaction,


SO2Cl2(g)SO2(g)+Cl2(g)

is increased. When equilibrium is re-established :

A
the mass of SO2(g) will decrease
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B
the mass of SO2Cl2(g) will increase
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C
the mass of Cl2(g) will increase
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D
the mass of Cl2(g) will remain unchanged
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Solution

The correct option is B the mass of Cl2(g) will increase
An increase in volume for the equilibrium having,

Kc=[SO2][Cl2][SO2Cl2]=[mole of SO2][mole of Cl2][mole of SO2Cl2]×Volume

will increase the mole of Cl2 or SO2 to maintain Kc values constant.

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