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Question

The volume of the reaction vessel containing an equilibrium mixture is increased in the following reaction:
SO2Cl2 (g)SO2 (g)+Cl2 (g)
When equilibrium is re-established:

A
The amount of Cl2 remains unchanged.
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B
The amount of Cl2 increases.
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C
The amount of SO2Cl2 increases.
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D
The amount of SO2 decreases.
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Solution

The correct option is B The amount of Cl2 increases.
Checking Δng for the given reaction:

SO2Cl2 (g)SO2 (g)+Cl2 (g)

Δng=21=1 (i.e.Δng>0)

For Δng>0 when volume is increased, ngV the reaction goes where ngV i.e. the reaction goes where ng .
It increases in the forward direction.
So, the reaction goes in forward direction.
Hence, when equilibrium is re-established, the amount of products formed increases .
Amount of Cl2 increases.

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