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Question

The volume of water needed to dissolve 1 mg of PbSO4(Ksp=1.44×108M2) at 25 C is approximately:
(molar mass of Pb=207 g/mol)

A
10 mL
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B
27 mL
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C
43 mL
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D
80 mL
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Solution

The correct option is B 27 mL
Solubility of PbSO4=Ksp=1.44×108=1.2×104 MSolubility of PbSO4=1.2×104×303×103=36.36 mg L1Volume of water needed to dissolve 1 mg of PbSO4=100036.36=27.5 mL

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