The wave number of the energy emitted when electron comes from fourth orbit to second orbit in hydrogen is 20,397cm−1. The wave number of the energy for the same transition in He+ is
A
5,099cm−1
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B
20,497cm−1
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C
40,994cm−1
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D
81,588cm−1
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Solution
The correct option is D81,588cm−1 Using 1λ=¯v=RZ2(1n21−1n22)⇒¯v∞Z2⇒¯v2¯v1=(Z2Z1)2=(Z1)2=4⇒¯v2=¯v×4=81588cm−1