The wave number of the first balmer line of Li2+ ions is 1,36,800 cm−1. The wavelenght of the first line of Balmer series of hydrogen atom is (in cm−1)
15,200
Atomic number of Li2+ is +3
1λ=RnZ2(1n21-1n22)
1,36,800=Rn×9(122-132)
1λ of H-atom =Rn(122-132)=1,36,8009
=15200 cm−1