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Question

The wavelength corresponding to a transition when electron falls from certain quantum level to the ground state of an He+ ion is 24.31 nm. Find the ratio of velocity of the electron in the next quantum level to that of velocity of light?

A
1:228
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B
1:524
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C
1:344
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D
1: 160
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Solution

The correct option is C 1:344
Given: λ=24.31 nm
we know,
1λ=RH×Z2[1n211n22]124.31×107=109678×22(1121n22)
n216.05
n4
n2=4 as n has to be an integer
so, next level n=5
velocity of electron in 5th level of He+,Vn=2.18×108Zncm/s=2.18×108×25 = 8.72×107cm/s
so ratio will be:
velocity of the electron in 5thlevel : velocity of light
= 8.72×107:3×1010
= 1:344

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