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Question

The work done during combustion of 9×102Kg of ethane, C2H6 (g) at 300 K is:
(Given: R 8.314 J deg1,mol1, atomic mass C = 12, H = 1)

A
+6.236 kJ
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B
- 6.236 kJ
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C
+18.71 kJ
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D
- 18.71 kJ
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Solution

The correct option is D +18.71 kJ
2C2H6(g)+7O2(g)4CO2(g)+6H2O(l)

C2H6(g)+3.5O2(g)2CO2(g)+3H2O(l)

Δn=2(1+3.5)=2.5
Molar mass of ethane =2(12)+6(1)=30 g/mol
9×102kg ethane =9×102kg×1000g/kg=90g
90 g ethane =90g30g/mol=3mol ethane.
For 1 mole of ethane, Δn=2.5
For 3 mole of ethane, Δn=2.5×3=7.5
Work done ,W=ΔnRT
W=(7.5)×8.314J/mol/K×300K
W=18707J
W=18.71kJ

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