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Question

The work done in an open vessel at 300 K, when 112 g iron reacts with dil HCl is :

A
1200 cal
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B
600 cal
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C
300 cal
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D
200 cal
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Solution

The correct option is A 1200 cal
Fe+2HClFeCl2+H21 mol 1 mol11256=2 mol 2 molNow,V2=VH2and V1=0
(For solid + liquid state)
Work done =p(v2v1)=p(H20)=pVH2=nH2RT=2×2×300=1200 cal

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