The work function for caesium atom is 1.9 eV. Calculate (a) the threshold wavelength and (b) the threshold frequency of the radiation. If the caesium element is irradiated with a wavelength 500 nm, calculate the kinetic energy and the velocity of the ejected photoelectron.
It is given that the work function ( W0 ) for caesium atom is 1.9 eV.
(a) From the W0=hcλ0 expression, we get:
λ0=hcW0
Where,
λ0 = threshold wavelength
h = Planck’s constant
c = velocity of radiation
Substituting the values in the given expression of (λ0 ):
λ0=(6.626×10−34Js)(3.0×108ms−1)1.9×1.602×10−19Jλ0=6.53×10−7m
Hence, the threshold wavelength λ0 is 653 nm. (b) From the expression, W0=hv0, we get:
v0=W0h
Where, ν0 = threshold frequency
h = Planck’s constant
Substituting the values in the given expression of ν0:
v0=1.9×1.602×10−19J6.626×10−34Js(1eV=1.602×10−19J)v0=4.593×1014s−1
Hence, the threshold frequency of radiation (ν0) is 4.593 × 1014s–1.
(c) According to the question:
Wavelength used in irradiation (λ) = 500 nm
Kinetic energy = h (ν – ν0 )
=hc(1λ−1λ0)=(6.626×10−34Js)(3.0×108ms−1)(λ0−λλλ0)=(1.9878×1026Jm)[(653−500)10−9m(653)(500)10−18m2]=(1.9878×10−26J)(153×109)(653)(500)=9.3149×10−20J
Kinetic energy of the ejected photoelectron = 9.3149 × 10–20J
Since K.E =12mv2=9.3149×10−20Jv=√2(9.3149×10−20J)9.10939×10−31kg=√2.0451×1011m2s−2v=4.52×105ms−1
Hence, the velocity of the ejected photoelectron (v) is 4.52 × 105ms–1.