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Question

The work function for caesium atom is 1.9 eV. Calculate (a) the threshold wavelength and (b) the threshold frequency of the radiation. If the caesium element is irradiated with a wavelength 500 nm, calculate the kinetic energy and the velocity of the ejected photoelectron.

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Solution

It is given that the work function ( W0 ) for caesium atom is 1.9 eV.
(a) From the W0=hcλ0 expression, we get:
λ0=hcW0
Where,
λ0 = threshold wavelength
h = Planck’s constant
c = velocity of radiation
Substituting the values in the given expression of (λ0 ):
λ0=(6.626×1034Js)(3.0×108ms1)1.9×1.602×1019Jλ0=6.53×107m
Hence, the threshold wavelength λ0 is 653 nm. (b) From the expression, W0=hv0, we get:
v0=W0h
Where, ν0 = threshold frequency
h = Planck’s constant
Substituting the values in the given expression of ν0:
v0=1.9×1.602×1019J6.626×1034Js(1eV=1.602×1019J)v0=4.593×1014s1
Hence, the threshold frequency of radiation (ν0) is 4.593 × 1014s1.
(c) According to the question:
Wavelength used in irradiation (λ) = 500 nm
Kinetic energy = h (ν – ν0 )
=hc(1λ1λ0)=(6.626×1034Js)(3.0×108ms1)(λ0λλλ0)=(1.9878×1026Jm)[(653500)109m(653)(500)1018m2]=(1.9878×1026J)(153×109)(653)(500)=9.3149×1020J
Kinetic energy of the ejected photoelectron = 9.3149 × 1020J
Since K.E =12mv2=9.3149×1020Jv=2(9.3149×1020J)9.10939×1031kg=2.0451×1011m2s2v=4.52×105ms1
Hence, the velocity of the ejected photoelectron (v) is 4.52 × 105ms1.


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