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Question

There is a mixture of three solid compounds A,B and C. Out of these compounds A and C are soluble in water and compound C is sublimable as well. In what sequence, the following techniques can be used for their effective separation?
I. Filtration
II. Sublimation
III. Crystallisation from water extract
IV. Dissolution in water

A
(II), (I), (IV), (III)
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B
(IV), (I), (II), (III)
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C
(I), (II), (III), (IV)
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D
(II), (IV), (I), (III)
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Solution

The correct option is D (II), (IV), (I), (III)
A+B+C is a mixture. C is soluble and sublimable. So, there's no use of using dissolution first.
C can be separated using sublimation technique. A and B can be separated by dissolution in water followed by filtration. A is soluble and B is insoluble. After filtration B can be obtained and A can be obtained by crystallisation.

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