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Question

There is a mixture of three solid compounds A, B and C. Out of these compounds A and C are soluble in water and compound C is sublimable also. In what sequence the following techniques can be used for their effective separation?


I. Filtration
II. Sublimation
III. Crystallisation from water extract
IV. Dissolution in water

A
(II), (I), (IV), (IIl)
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B
(IV), (I), (II), (lII)
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C
(I), (Il), (III), (IV)
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D
(II), (IV), (I), (III)
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Solution

The correct option is D (II), (IV), (I), (III)
C is sublimable thus it can be separated from a given mixture by sublimation.

The remaining mixture of A and B can be put in water compound B is insoluble in water can be separated out by filtration.

Compound A can be recovered from filtrate by crystallisation.

Hence, the correct order is II, IV, I, III.

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