Thermal decomposition of a compound is of first order . If 50% of a sample of compound is decomposed in 120 minutes, how long will it take for 90% of compound to decompose ?
A
299 min
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B
399 min
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C
99 min
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D
9.9 min
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Solution
The correct option is B 399 min k=0.693t12=0.693120=5.77×10−3min−1 ∴t=2.303klog10010=399min