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Question

Thermodynamically, which form of carbon is the most stable?


A

Coal

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B

Graphite

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C

Fullerenes

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D

Diamond

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Solution

The correct option is B

Graphite


Explanation for the correct option:

(B) Graphite

  • Graphite contains Carbon atoms having delocalized electrons in each carbon atom.
  • The delocalization of the electrons lowers the energy of the whole system or structure of Graphite.
  • This leads to stronger bonds between the carbon atoms of the structure.
  • This further leads to Thermodynamic stability, which refers to a system being in its lowest energy state or being in chemical equilibrium with the environment.

Explanation for the incorrect :

(A) Coal

  • Coal is an Amorphous allotropic form of carbon.
  • It does not have a defined structure or geometry.
  • Hence, It is less stable than Graphite having a crystalline form.

(C) Fullerenes

  • A Fullerene is a crystalline allotrope of carbon whose molecules consist of carbon atoms connected by single bonds or double bonds.
  • It has loose stability which helps it take part in the reactions.
  • Hence, it is less stable than Graphite.

(D) Diamond

  • Diamond is a crystalline allotrope of Carbon.
  • It has a rigid and compact structure due to which it takes more energy and time to be formed.
  • It has a high enthalpy of formation than Graphite.
  • Thus, is less thermodynamically stable than Graphite.

Hence, correct option is (B), Graphite is the most thermodynamic stable form of Carbon.


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