If we look at the given figure, we can see C1 and C2 are in series, so the resultant capacitance for this combination is given by C4
⇒1C4=1C2+1C1
⇒C4=2μF
now the circuit will be look like as new drawn figure. now we can see C4 is in Parallel withC3, So the equivalent capacitance between A and B is given by CAB
⇒CAB=C3+C4⇒CAB=10μF+2μF=12μF
so the total charge flowing through the battery is Qtotal
⇒Qtotal=CABV⇒Qtotal=12×50=600μC
Assume that charge flowing in chain 1 is Q1 and in chain 2 isQ2 and we can see both the chains are in parallel with each other then the potential difference will be also same at the ends.
⇒Qtotal=Q2+Q1=600μC...(1)
⇒Q1C4=Q2C3
⇒Q12=Q210
⇒Q2= 5Q1
from equation (1) and (2)
⇒Q1=100μC and Q2=500μC
now the charge on C1 will be q1 equal to Q1
because in a series of capacitors same amount of charge will flow so the charge on C1 is
⇒q1=100μC