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Question

Three photons coming from emission spectra of hydrogen sample are picked up. Their energies are 12.1eV,10.2eV and 1.9eV . These photons must come from

A
a single atom
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B
two atoms
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C
three atom
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D
either two atoms or three atoms
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Solution

The correct option is D either two atoms or three atoms
These energies are due the hydrogen electron dropping down from a higher excited energy level to a lower level .. so they must each be photons from a single atom (electrons don't move between atoms when they change energy levels)
12.1eV .. emitted when an electron drops from level n=3 (1.51 eV) to n=1 (13.60eV)
[excess energy 13.6 - 1.51 = 12.09eV]
10.2 eV .. emitted for a transition between n=2 (3.4eV) and n=1 (13.6eV)
1.9eV .. emitted for a transition between n=3 (1.51eV) and n=2 (3.40eV)

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