The electronic configuration of Ti3+→1s22s22p63s23p63d1.
It has a d1 configuration. While acting as a reducing agent, it gets oxidized to Ti4+ (electronic configuration, d0). This configuration is a more stable inert gas configuration.
Co3+ is an oxidizing agent.
A common oxidation state of Co for simple compounds is +2.
The electronic configuration ofCo3+→1s22s22p63s23p63d6.
It tends to accept two electrons and get reduced to achieve d7 configuration which is a more stable configuration because the repulsion between the electrons of the two electron-pairs is less than for Co where there are 3 electron-pairs.