Titanium tetrachloride, TiCl4, is a liquid at room temperature and has a very high vapor pressure. Which statement best explains these observations?
A
Titanium tetrachloride is an ionic compound, with Ti4+ and Cl− ions arranged in a lattice
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B
Titanium tetrachloride is a molecular substance, with TiCl4 molecules held together by covalent bonds.
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C
The bonding in titanium tetrachloride is metallic, with a sea of electrons being shared equally between all the atoms in a sample.
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D
Titanium tetrachloride is a network covalent substance, with an essentially infinite lattice of covalently-bonded Ti and Cl atoms
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E
Titanium tetrachloride is simply a mixture of titanium atoms and chlorine atoms, which are not bonded to each other in any particular way.
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Solution
The correct option is B Titanium tetrachloride is a molecular substance, with TiCl4 molecules held together by covalent bonds. Titanium tetrachloride consist of tetrahedral TiCl4 molecules weakly held together by vander walls forces.TiCl4 melts at at −230C.The wealk intermolecular forces constitute the points of structural weakness in such a crystal, and fusion at relatively low temperatures.