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Question

Titration of a 0.7439 g sample of impure Na2B4O7.10H2O (borax) requires 31.64 mL of 0.108MHCl for the reaction. The result of this analysis in terms of percentage is (in nearest integer) :
(Molecular weight of B=11 g/mol)

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Solution

Number of moles of HCl =0.108×31.641000=0.00342 moles

1 mole borax corresponds to 2 moles of HCl.

Number of moles of borax =0.003422=0.00171 moles

Molar mass of Na2B4O7.10H2O=202+180=382 g/mol

Percentage of borax =0.00171×3820.7439×100=87.73% 88%

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