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Question

To form alkane isonitrile, alkyl halide is reacted with:

A
KCN
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B
AgCN
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C
HCN
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D
NH4CN
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Solution

The correct option is A AgCN
To form alkane isonitrile, an alkyl halide is reacted with AgCN. Thus, methyl bromide is heated with an alcoholic solution of silver cyanide to form methyl isonitrile is obtained.

CH3Br+AgCN(alc)CH3NC+AgBr

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