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Question

To prepare a pure sample of n-hexane using sodium metal as one reactant, the other reactant or reactants will be:

A
ethyl chloride and n-butyl chloride
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B
methyl bromide and n-pentyl bromide
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C
n-propyl bromide
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D
ethyl bromide and n-butyl bromide
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Solution

The correct option is C n-propyl bromide

2CH3CH2CH2Brnpropyl(bromide)+2Na Ether CH3CH2CH2CH2CH2CH3+2NaBrnHexane

This is Wurtz reaction.

The reaction forms R-R' , so it is possible to use Options 1 and 2 to form hexane.
But those 2 can also form a number of other products, which is not feasible.


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