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Question

To prepare tertiary butyl ethyl ether by Williamson’s synthesis, the reactants needed are:–

A
sodium ethoxide & sodium tertiary butoxide
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B
sodium ethoxide & tertiary butyl bromide
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C
Sodium terliary butoxide & ethyl bromide
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D
Ethyl alcohol & tertiary butyl alcohol
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Solution

The correct option is C Sodium terliary butoxide & ethyl bromide
It is a simple example of Williamson’s ether synthesis.
Alkyl halides on treatment with an alkoxide ion tend to undergo substitution to form ethers.
Thus, sodium tertiary butoxide & ethyl bromide is the right choice.

(CH3)3 CONa++CH3 CH2 Br(CH3)3COCH2 CH3+Na Br

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